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Since freckles use the face mesh as a base and accessories use the body (theoretically), I don't think you can just change the category like that. Why not just make the freckles into working topical details (the kind that you tick in CAS) instead?
It's not that hard, it just requires a bit of hex-editing.
I have a video tutorial on that here:
http://thesimsupply.com/showthread.php?tid=228
The only downside is, you might need Rez Delnava's hack to get them to show up which hasn't been updated. However, just having one extra freckle probably won't cause too much of a problem.
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