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Get some custom sliders - ya can ask for recommendations for some in the Where Can I Find forum.
Find some nice default replacement eyes/skins (or non-defaults, if you prefer) that you like the look of. If you need other custom content (hairstyles or whatever) to complete the look, you can ask in Where Can I Find for that too.
Oh, and get Awesomemod, so you can see your sim as it'll look in-game in Create-a-Sim, without them smiling.
Other than that it's just a matter of playing with makeup, hair, skins, etc. as well as of course sculpting the face using the sliders. And there's no real trick to that besides keeping working on it till it's good.
my simblr (sometimes nsfw)
“Dude, suckin’ at something is the first step to being sorta good at something.”
Panquecas, panquecas e mais panquecas.